杨开吉,张颖,魏强,等. 海上油田开发用抗温抗盐乳液聚合物研制与性能评价[J]. 石油钻探技术,2024,52(3):1-10. DOI: 10.11911/syztjs.2024010
引用本文: 杨开吉,张颖,魏强,等. 海上油田开发用抗温抗盐乳液聚合物研制与性能评价[J]. 石油钻探技术,2024,52(3):1-10. DOI: 10.11911/syztjs.2024010
YANG Kaiji, ZHANG Ying, WEI Qiang, et al. Emulsion polymer with temperature resistance and salt resistance used in offshore oilfield development [J]. Petroleum Drilling Techniques, 2024, 52(3):1-10. DOI: 10.11911/syztjs.2024010
Citation: YANG Kaiji, ZHANG Ying, WEI Qiang, et al. Emulsion polymer with temperature resistance and salt resistance used in offshore oilfield development [J]. Petroleum Drilling Techniques, 2024, 52(3):1-10. DOI: 10.11911/syztjs.2024010

海上油田开发用抗温抗盐乳液聚合物研制与性能评价

Emulsion Polymer with Temperature Resistance and Salt Resistance Used in Offshore Oilfield Development

  • 摘要: 为满足海上油田开发对聚合物溶解速度、抗温和抗盐性能的要求,使用自制的高效聚合物乳化剂和热稳定剂,采用低温复合引发体系多段引发,制备了超高相对分子质量的速溶抗温抗盐型乳液聚合物,分析了制备工艺,助溶剂、功能单体和热稳定剂加量对聚合物性能的影响。结果表明,通过工艺优化可制备得到相对分子质量2 200万~2 400万的聚合物,尿素和硫酸钠可显著提高超高相对分子质量抗温抗盐乳液聚合物的溶解速度;聚合时添加N,N-二甲基丙烯酰胺、自制热稳定剂和2-丙烯酰胺-2-甲基丙磺酸钠,可显著提高聚合物的抗温抗盐性能。采用电镜、激光粒度仪、GPC和TGA等方法,评价了超高相对分子质量抗温抗盐型乳液聚合物的结构及性能,结果表明,制备的聚合物乳胶粒分布均匀、相对分子质量分布窄和耐温性能好,在矿化度35000 mg/L、温度75 ℃条件下,乳液聚合物的30 d黏度保留率大于90%。研究表明,超高相对分子质量抗温抗盐型乳液聚合物具有速溶、相对分子质量高和抗温抗盐性能好的特点,可以用于海上油田驱油开发。

     

    Abstract: In order to meet the large demand for instant, temperature resistant and salt resistant polymers in offshore oil field development, research on ultra-high molecular weight temperature resistant and salt resistant lotion polymers was carried out. The super high molecular weight, instant, temperature resistant and salt resistant lotion polymer was prepared by using self-made high efficient polymer emulsifier and self-made heat stabilizer and low-temperature composite initiation system. Studied the effects of preparation process, co solvents, functional monomers, and thermal stabilizers on product performance. The results show that the molecular weight can be 22 million to 24 million through process optimization. Urea and sodium sulfate can significantly improve the dissolution rate of ultra-high molecular weight temperature resistant and salt resistant lotion polymer. Adding N,N-dimethylacrylamide, self-made heat stabilizer and sodium 2-acrylamide-2-methylpropane sulfonate during polymerization can significantly improve the temperature resistance and salt resistance of the product. The structure and properties of ultra-high molecular weight temperature resistant and salt resistant lotion polymers were characterized by electron microscopy, laser particle size analyzer, GPC and TGA. The research results indicate that the prepared polymer latex has uniform particle distribution, narrow molecular weight distribution, and good temperature resistance. The viscosity retention rate of the polymer lotion in one month is more than 90% at 35000 mg/L salinity and 75 ℃. Ultra high molecular weight temperature resistant and salt resistant lotion polymer has instant solubility, high molecular weight, good temperature resistance and salt resistance, and can be widely used in offshore oil field development.

     

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