缓慢释放固态酸化剂ZY-Y的制备与现场应用

Preparation and Field Application of Slow-Release Solid Acidifier ZY-Y

  • 摘要: 针对常规酸化酸液反应快、改造半径小、难以实现远井地带储层有效改造,或者造成酸液浪费,现有固态酸耐高温缓速性能差且存在环保隐患等问题,以碳酰二胺脲、发烟硫酸为原料合成固态酸颗粒,搭配可降解材料喷淋包衣制备缓慢释放固态酸化剂ZY-Y。室内性能试验结果表明,ZY-Y 90 ℃时的酸岩持续反应时长350 min,为胶凝酸的7.1倍,溶蚀率超93%,具有良好的抗地层水稀释能力,可实现远井地带储层改造,且不均匀刻蚀表现明显,有利于提高导流能力。西部油田8口井深超6 500 m的深井现场应用结果显示,平均油井增产率51.6%,典型井例累计增油超12 000 t,综合酸化改造成本降低 21.9%。研究与应用表明,缓慢释放固态酸化剂ZY-Y具有良好的缓速性能、溶蚀效率和环保经济性,可实现碳酸岩储层深部酸化改造,适合老井中远地层解堵增产,具备大范围推广价值。

     

    Abstract: To address the drawbacks of conventional acidizing fluids, including fast acid-rock reaction rates, limited effective stimulation radius, insufficient reservoir modification in far-well zones, excessive acid waste, as well as poor high-temperature retarding performance and environmental hazards of existing solid acids, solid acid particles were synthesized using carbamide and oleum as raw materials, and a slow-release solid acidifier ZY-Y was fabricated via spray coating with degradable materials. Laboratory performance tests reveal that at 90 ℃, the continuous acid-rock reaction duration of ZY-Y reaches 350 minutes, 7.1 times that of gelled acid, with a rock dissolution rate exceeding 93%. It boasts excellent resistance to formation water dilution, enabling effective stimulation of far-well reservoirs. Moreover, it creates prominent uneven etching, which helps enhance fracture conductivity. Field applications in 8 deep wells over 6,500 meters deep in western oilfields demonstrate an average oil production increment rate of 51.6%, and a typical well achieved a cumulative oil increment of more than 12,000 tons, with the overall acidizing stimulation cost reduced by 21.9%. Laboratory research and field practices verify that the slow-release solid acidifier ZY-Y delivers outstanding retarding capacity, high dissolution efficiency, environmental friendliness and economic benefits. It can realize deep acidizing modification of carbonate reservoirs, is suitable for plug removal and production enhancement in intermediate and far zones of mature wells, and possesses great value for large-scale popularization.

     

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