黏性微动力乳化聚合物/表面活性剂体系的制备和驱油效果研究

Preparation and Oil Displacement Performance of Viscous and Microdynamic Emulsifying Polymer/Surfactant System

  • 摘要: 为了提高驱替相黏度和降低稠油黏度,研究制备了一种黏性微动力乳化二元驱油剂。该体系由耐温抗盐聚合物BM和非离子表面活性剂AC1205混合而成,兼具水溶液增黏与稠油微动力乳化降黏的双重功能;系统评价了体系组成对溶液性质的影响,并分析了体系的宏观与微观驱油效果。结果表明,AC1205对BM溶液的黏度影响较小,当AC1205质量分数为0.2%~0.3%、油水比1∶9~5∶5时,BM/AC1205混合体系均能够在微动力下乳化稠油,因此,可根据BM的质量分数−黏度关系灵活配制驱油剂的黏度。基于上述特性,该体系通过聚合物增黏与表面活性剂乳化降黏的协同作用,同步调节了油水两相黏度,从而大幅降低了水油流度比。岩心驱油实验表明,该黏性微动力乳化体系可在水驱基础上使稠油采收率提高18.7百分点。研究结果为稠油油藏高效开发提供了新的技术途径。

     

    Abstract: To enhance the viscosity of the displacement phase and reduce the viscosity of heavy oil, a viscous and microdynamic emulsifying binary oil displacement agent was developed. This system is formulated by mixing the temperature-tolerant and salt-resistant polymer BM with nonionic surfactant AC1205, which integrates dual functions of increasing viscosity of aqueous solutions and reducing viscosity of heavy oil through microdynamic emulsification. The influence of system composition on solution properties was systematically evaluated, and both macroscopic and microscopic oil displacement efficiencies were analyzed. Results show that AC1205 has a minor impact on the viscosity of BM solutions. When the mass fraction of AC1205 ranges from 0.2% to 0.3% and the oil–water ratio varies from 1∶9 to 5∶5, the BM/AC1205 mixed system can effectively emulsify heavy oil under microdynamic conditions. Accordingly, the viscosity of the oil displacement agent can be flexibly adjusted based on the mass fraction–viscosity relationship of BM. Leveraging these characteristics, the system simultaneously modulates oil and water phase viscosities through the synergistic effect of polymer-induced viscosity enhancement and surfactant emulsification-induced viscosity reduction, thereby significantly lowering the water–oil mobility ratio. Core flooding experiments further verify that this viscous and microdynamic emulsification system enhances heavy oil recovery by 18.7 percentage points compared with conventional water flooding. The research results have provided a new technical approach for the efficient development of heavy oil reservoirs.

     

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