渤海油田油井缓冲直排酸体系的研究与应用

Research and application of buffered direct baclflow acid fluid in Bohai oilfield oil wells

  • 摘要: 渤海油田在生产过程中易因结垢造成产能下降,常规酸化解堵存在残酸返排需中和、易导致原油乳化、设备腐蚀及生产流程中断等问题,而现有螯合中性解堵剂普遍存在溶蚀能力不足、易产生二次沉淀等缺陷。针对上述难题,研发了一种缓冲直排酸解堵体系,该体系以低分子羧酸及其铵盐为主剂,复配少量盐酸、氟化氢铵、氢氟酸及HEDP与柠檬酸复合铁离子稳定剂,通过二次pH值调节机制实现残酸 pH 稳定在5~7,可直接返排。性能评价表明,缓冲直排酸解堵体系前置液对碳酸钙溶蚀率达75.25%,处理液对膨润土及现场岩屑溶蚀率分别为34.70%和15.73%~20.91%,铁离子稳定能力达175 mg/L,综合性能优于或接近常规酸液。该体系在渤海油田多口井现场应用后,增油倍数达1.38~2.18倍,返排液无需中和即可直接进入生产流程,解堵效果与流程适应性良好,为海上油田高效安全酸化解堵提供了新技术支撑。

     

    Abstract: In response to the problems of the impact of residual acid backflow on the production process and the insufficient corrosion performance of chelating neutral plugging removal agents during the acidizing plugging removal process of oil wells in the Bohai Oilfield, a new type of buffered direct - discharge acid system was developed. This system uses carboxylic acid with a low relative molecular mass and its ammonium salt as the main components of the buffer solution. A low - mass - fraction hydrochloric acid is introduced as the pre - fluid to improve the initial corrosion efficiency. Ammonium hydrogen fluoride, hydrofluoric acid, iron ion stabilizers (hydroxyethylidene diphosphonic acid and citric acid) suitable for high pH values and other additives are compounded in the treatment fluid. Combined with the secondary pH adjustment process, the unity of high corrosion performance and backflow compatibility is achieved. The experimental results show that the pH value of the pre - fluid of the system is 0.300, the pH of the treatment fluid is 3.534, the pH of the residual acid is stable between 5 and 7, the corrosion rates of calcium carbonate, bentonite and cuttings reach 75.25%, 34.70% and 15.73% - 20.91% respectively, and the iron ion stabilization capacity reaches 175 mg/L. Field application shows that this system does not require alkali neutralization, the backflow fluid can directly enter the production process, the production increase ratio reaches 1.38 - 2.18 times, and the effect is comparable to that of conventional acidizing. This research provides a new technical path for efficient and environmentally friendly acidizing plugging removal in offshore oilfields.

     

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