超高强度凝胶氧化破胶降解动力学研究

Degradation kinetics of ultra-high strength gel with oxidative gel breakage

  • 摘要: 为明确单体聚合类凝胶在暂堵作业结束后的氧化破胶降解机理,开展了凝胶氧化破胶降解动力学研究。运用Horowitz-Metzger、Coats-Redfern和Flynn-Wall-Ozawa模型,计算得到超高强度凝胶(USGel)降解动力学参数,对比分析得到适合USGel的降解动力学模型;结合扫描电镜、傅里叶红外光谱分析等实验,揭示了破胶剂破碎降解USGel的机理,并得到低、中、高温修正后的降解预测模型。研究结果表明,该模型适用于预测USGel中高温降解时间;根据凝胶降解机理,破胶剂逐步消耗USGel酰胺基团的氨基(—NH2)和羧酸基团的羟基(—OH)等化学键,聚合物分子链逐步断裂,最终USGel破碎变成液体。研究结果为改进油气井暂堵破胶技术提供了理论依据。

     

    Abstract: (Aim) In order to clarify the mechanism of oxidative gel degradation of monomer-polymerised gels at the end of temporary plugging operations, a kinetic study on the oxidative gel degradation of gels was carried out. (Methods) Using the Horowitz-Metzger, Coats-Redfern and Flynn-Wall-Ozawa models, the degradation kinetic parameters of ultra-high-strength gel (USGel) were calculated, and the degradation kinetic model suitable for USGel was obtained by comparative analysis; combining with the scanning electron microscope, Fourier infrared spectroscopy analysis and other experiments, the mechanism of the degradation of USGel by breaking of gel breakers was revealed, were obtained by using Semenov's equation to obtain the modified degradation prediction model for low, medium, and high temperatures, which was suitable for predicting the time of degradation at medium and high temperatures of USGel by analysing the experimental data; and the degradation mechanism was clarified, the The gel-breaker gradually consumes the chemical bonds such as amino group (-NH2) and hydroxyl group (-OH) of amide group and carboxylic acid group in USGel, and the polymer molecular chain is gradually broken, and finally USGel is broken into liquid. (Conclusion) The results of the study provide a theoretical basis for the improvement of the temporary plugging and breaking technology of oil and gas wells.

     

/

返回文章
返回