冻土区裂隙性地层中水合物形成机理及相态研究

Formation Mechanism and Phase State of Hydrates in Fractured Layers of Permafrost

  • 摘要: 天然气水合物广泛充填于冻土地层裂隙中,钻探冻土地层裂隙中的天然气水合物需要先对其合成、分布和相态进行研究。基于祁连山地区裂隙性地层特征制作了人工岩心,进行了天然气水合物的形成及相平衡实验;利用A.H.Mohammadi提出的天然气水合物热力学模型,预测了NaCl和KCl溶液中天然气水合物的相平衡条件,并分析其在含盐低温钻井液条件下的相平衡偏移问题。实验得出,天然气水合物主要分布在岩心的裂隙面及端面;压力为4 MPa时,质量分数为5%和10%的NaCl溶液中天然气水合物的相平衡温度分别降低了约2.2 K和4.6 K,质量分数为10%的KCl溶液中天然气水合物的相平衡温度降低了3.4 K。研究结果表明:冻土地层裂隙中的天然气水合物由大量块状水合物和极少量孔隙充填型水合物组成,其相平衡条件与宏观水相中一致,在相同盐度下NaCl对天然气水合物相平衡的影响大于KCl。

     

    Abstract: Natural gas hydrate is widely distributed in the fractured layers of permafrost. In order to explore gas hydrate in the fractured layers of permafrost, it is necessary to study its formation, distribution and phase state. In this paper, the formation and phase equilibrium experiments of gas hydrate were conducted on the artificial cores which were prepared in reference to the characteristics of fractured layers in the area of Qilian Mountains. The phase equilibrium of hydrate in NaCl and KCl solutions were predicted according to the gas hydrate thermodynamic model created by A.H.Mohammadi, and the phrase equilibrium migration of hydrate in drilling fluids under the conditio of low temperature and salt bearing was discussed. It is shown by experimental results that gas hydrate is mainly distributed at the fracture surface and end surface of samples. When the pressure is 4 MPa, the phase equilibrium temperature of hydrate in NaCl solutions that have mass fraction of 5% and 1% declined about by 2.2 K and 4.6 K, respectively, and that in KCl solution with mass fraction of 10% decreased by 3.4 K. Research results indicated that the gas hydrate in fractured layers of permafrost is mostly in the massive form and slightly filled in the pores, and its phase equilibrium condition is consistent with that in macroscopic water phase. And under the same salinity, the effect of NaCl on the phase equilibrium of gas hydrate is greater than that affected by KCl.

     

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