Study on Mechanism of the Fracturing Fluid Performance Improvement and Oil Displacement Using Nanomaterials

LIU Jiankun; JIANG Tingxue; HUANG Jing; WU Chunfan; JIA Wenfeng; CHEN Chen

doi:10.11911/syztjs.2021118

Volume 50 Issue 1

Mar. 2022

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Petroleum Drilling Techniques > 2022 > 50(1): 103-111. > DOI: 10.11911/syztjs.2021118

LIU Jiankun, JIANG Tingxue, HUANG Jing, WU Chunfan, JIA Wenfeng, CHEN Chen. Study on Mechanism of the Fracturing Fluid Performance Improvement and Oil Displacement Using Nanomaterials[J]. Petroleum Drilling Techniques, 2022, 50(1): 103-111. DOI: 10.11911/syztjs.2021118

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Study on Mechanism of the Fracturing Fluid Performance Improvement and Oil Displacement Using Nanomaterials

LIU Jiankun^{1, 2,},
JIANG Tingxue^{1, 2},
HUANG Jing^{1, 2},
WU Chunfan^{1, 2},
JIA Wenfeng^{1, 2},
CHEN Chen^{1, 2}

1.
State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing, 102206, China
2.
Sinopec Research Institute of Petroleum Engineering, Beijing, 102206, China

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Received Date: October 22, 2020
Revised Date: October 31, 2021
Available Online: October 27, 2021

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Abstract

Abstract

To provide a theoretical basis for the development of functional fracturing fluids, SiO₂ was modified with C₈ and quaternary ammonium salt (QAS) on nanoscale (50 nm). The hydrophobic nanomaterial SiO₂-C₈ and hydrophobic charged nanomaterial SiO₂-QAS were synthesized. The compatibility, stability, and comprehensive performance of the SRFP polymer clean fracturing fluid systems were evaluated as nanomaterials SiO₂, SiO₂-C₈, and SiO₂-QAS were added. Quantitative simulation methods were employed to build the adsorption structure models and adsorption kinetics models of the nanomaterials on the sandstone surface. The adsorption and oil-water separation characteristics of nanomaterials on sandstone surfaces were analyzed. The experimental and simulation results show that the three nanomaterials, SiO₂, SiO₂-C₈, and SiO₂-QAS, display favorable dispersion stability in fracturing fluids. They can effectively reduce the surface and interfacial tension and demonstrate good temperature and shear resistance. SiO₂-C₈ and SiO₂-QAS nanomaterials are beneficial to the replacement of oil molecules on the sandstone surface and the oil-water separation when they are added into fracturing fluids. The addition of nanomaterials SiO₂-C₈ and SiO₂-QAS can also effectively improve the performance of fracturing fluids, enhance oil displacement, and reduce oil saturation within the spread range of fracturing fluids. The research results can provide a theoretical basis for the development of functional fracturing fluids and a reference for fracturing design optimization and fracturing fluid selection for tight oil and shale oil.
- nanomaterial,
- clean fracturing fluid,
- oil displacement mechanism,
- tight sandstone,
- surface tension

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